1-(2-Benzyl-1,5-dimethyl-6,7,8-trioxabicyclo[3.2.1]octan-2-yl)ethan-1-ol
نویسندگان
چکیده
The title compound, 1-(2-Benzyl-1,5-dimethyl-6,7,8-trioxabicyclo[3.2.1]octan-2-yl)ethan-1-ol, was synthesized for the first time by selective reduction in keto ozonide under action of strong reducing agent LiAlH4. product characterized NMR, IR, HRMS, and elemental analysis.
منابع مشابه
2-(2-Hydroxy-2-phenylethyl)-1-methylcyclopropan-1-ol
The asymmetric unit of the title compound, C(12)H(16)O(2), contains two independent mol-ecules in which the dihedral angles between the benzene and cyclo-propane rings are 75.9 (3) and 76.3 (3)°. In the crystal, the mol-ecules are connected by O-H⋯O hydrogen bonds into a three dimensional supra-molecular structure.
متن کامل2-(1-Adamantyl)-1,3-diphenylpropan-2-ol
In the title compound, C(25)H(30)O, the adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.15 (9)-111.55 (9)°. The dihedral angle between the benzene rings is 46.91 (4)° and the conformation is stabilized by a weak intra-molecular C-H⋯π inter-action.
متن کامل1-[(2-Methylpiperidin-1-yl)(phenyl)methyl]naphthalen-2-ol
In the title compound, C(23)H(25)NO, an intra-molecular O-H⋯N hydrogen bond defines the mol-ecular conformation; the naphthol mean plane and the benzene ring form a dihedral angle of 75.8 (2)°. The piperidine ring adopts a chair conformation. The crystal packing exhibits no short inter-molecular contacts.
متن کاملDimethyl 2-(1-benzyl-2-oxoindolin-3-ylidene)-1,3-dithiole-4,5-dicarboxylate
In the title compound, C(22)H(17)NO(5)S(2), the dithiole and oxindole rings are almost coplanar [dihedral angle = 2.71 (8)°] and the phenyl ring makes a dihedral angle of 73.65 (5)° with the oxindole ring. Inter-molecular π-π contacts between adjacent oxindole and dithiole rings [centroid-centroid distance = 3.7273 (11) Å] stabilize the crystal packing.
متن کامل(S)-2-(1-Methylindolin-2-yl)-1,3-diphenylpropan-2-ol
The five-membered ring in the the title mol-ecule, C(24)H(25)NO, fused with the phenyl-ene ring, is almost planar (r.m.s. deviation = 0.023 Å), with the methyl-ene C atom deviating most from this mean plane [0.031 (1) Å]. The tertiary N atom shows a flattened pyramidal configuration [Σ(angles at N) = 350.3 (6)°].
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ژورنال
عنوان ژورنال: Molbank
سال: 2022
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1532